Bis(diisopropylammonium) tetrachloridocuprate(II)
نویسنده
چکیده
In the title mol-ecular salt, (C(6)H(16)N)(2)[CuCl(4)], the Cu(II) ion adopts an extremely distorted tetra-hedral coordination geometry. All the ammonium H atoms are involved in N-H⋯Cl hydrogen bonds, which serve to link the cations and anions into chains propagating along the c-axis direction.
منابع مشابه
Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II)
In the crystal structure of the title salt, (C(5)H(9)N(2))(2)[CuCl(4)], the organic cations and the tetrahedral [CuCl(4)] anions are linked into a three-dimensional network by N-H⋯Cl hydrogen bonds. The two 2-ethyl imidazolium cations in the asymmetric unit differ in the orientation of the ethyl group, with N-C-C-C torsion angles of -170.0 (4) and -87.6 (5)°.
متن کاملBis(2-amino-4-methylpyridinium) tetrachloridocuprate(II)
The title compound, (C(6)H(9)N(2))(2)[CuCl(4)], contains a distorted tetra-hedral [CuCl(4)](2-) anion and two protonated amino-pyridinium cations. The geometries of the protonated amino-pyridinium cations reveal amine-imine tautomerism. The crystal packing is influenced by N-H⋯Cl and C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.635 (4) and 3.642 (4)°].
متن کاملBis(diisopropylammonium) naphthalene-1,5-disulfonate
In the title compound, 2C(6)H(16)N(+)·C(10)H(6)O(6)S(2) (2-), the cations and anions are associated via N-H⋯O and C-H⋯O hydrogen-bonding inter-actions.
متن کاملBis(4-fluoroanilinium) tetrachloridocuprate(II)
The crystal structure of the title compound, (C(6)H(7)FN)(2)[CuCl(4)], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl(6) octa-hedra. These are bonded together via N-H⋯Cl hydrogen bonds from the 4-fluoro-anilinium chains, which are almost perpendicular to the layers. The CuCl(4) dianions have two short Cu-Cl bonds [2.2657 (15) and 2.2884 (13) Å] and two longer...
متن کاملBis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
The title compound, (C(5)H(14)N(2))[CuCl(4)], was synthesized by hydro-thermal reaction of CuCl(2) with 1-methyl-piperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu-Cl distances in the tetrahedral anion are in the range 2.2360 (7)-2.2732 (7) Å. In the crystal, moderately strong and weak inter-molecular N-H⋯Cl hydrogen b...
متن کامل